The macrocyclic molecular catalyst (1) complexes primary ammonium ester salts and displays enhanced rates of intramolecular thiolysis of the bound substrates with structural selectivity for dipeptide esters and high chiral recognition for the (L) antipode of the enantiomeric glycyl–phenyl–alanine esters.
J. Lehn and C. Sirlin, J. Chem. Soc., Chem. Commun., 1978, 949 DOI: 10.1039/C39780000949
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