Issue 19, 1978

Unusual incorporation of the cyano group of t-butylcyanoketen into a cycloadduct. X-Ray structure of the pyrimido[1,6-e][1,3,5]dioxazine formed

Abstract

The cycloaddition of t-butylcyanoketen (1) and N-methylbenzylideneamine affords the binuclear heterocycle (5), which seems to result from the interception of the intermediate highly strained ketenimine (4) by an excess of (1); the crystal and molecular structure of (5) has been determined.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1978, 820-821

Unusual incorporation of the cyano group of t-butylcyanoketen into a cycloadduct. X-Ray structure of the pyrimido[1,6-e][1,3,5]dioxazine formed

E. Schaumann, H. Mrotzek and G. Adiwidjaja, J. Chem. Soc., Chem. Commun., 1978, 820 DOI: 10.1039/C39780000820

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