Unusual incorporation of the cyano group of t-butylcyanoketen into a cycloadduct. X-Ray structure of the pyrimido[1,6-e][1,3,5]dioxazine formed
Abstract
The cycloaddition of t-butylcyanoketen (1) and N-methylbenzylideneamine affords the binuclear heterocycle (5), which seems to result from the interception of the intermediate highly strained ketenimine (4) by an excess of (1); the crystal and molecular structure of (5) has been determined.
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