2-Phenylthioallyl alcohols (I) rearrange in acid to α-phenylthioethyl ketones (II) which, on oxidation and elimination, yield vinyl ketones; through a similar reaction sequence 2-phenylthioallenyl alcohols (IX) give the 2,4-dienones (XII).
R. C. Cookson and P. J. Parsons, J. Chem. Soc., Chem. Commun., 1978, 821 DOI: 10.1039/C39780000821
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