Mössbauer spectra of several bis(piperidine) and carbonylpiperidine haemochromes suggest that replacement of the axial amine by carbon monoxide causes pronounced changes in the iron–porphyrin bonding, i.e. causes a substantial cis-effect.
B. R. James, J. R. Sams, T. B. Tsin and K. J. Reimer, J. Chem. Soc., Chem. Commun., 1978, 746 DOI: 10.1039/C39780000746
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