Steric mechanism of formation of the PdCl π-allyl derivative from [6β-2H]cholest-4-ene
Abstract
[6β-2H]Cholest-4-ene reacts with [(PhCN)2PdCl2] to give the α 4–6 η and β 4–6 η PdCl derivatives with specifically syn 6-H, or 6-2H elimination, respectively.
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