The coupling pattern of illudin M and S, derived from [1,2-13C2]acetate, and the induced coupling from [1-13C]acetate, support their biosynthesis from farnesyl pyrophosphate; the illudin M–isoilludin M rearrangement has been shown to be a 1 : 2 methyl shift rather than a pinacolic rearrangement.
A. P. W. Bradshaw, J. R. Hanson and M. Siverns, J. Chem. Soc., Chem. Commun., 1978, 303 DOI: 10.1039/C39780000303
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