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Analysis of the MoLβ2,15(d–2p)X-ray emission peak from [Mo2Cl8]4– shows the presence of three molecular orbital energy levels, contributing to the Mo–Mo quadruple bond, together with a peak at a higher binding energy which is attributed to Mo–Cl bonding orbitals.
D. E. Haycock, D. S. Urch, C. D. Garner, I. H. Hillier and G. R. Mitcheson, J. Chem. Soc., Chem. Commun., 1978, 262 DOI: 10.1039/C39780000262
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