Issue 10, 1977
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Synthesis of secondary or tertiary alcohols by reactions of trialkylboranes with acyl carbanion equivalents

Rosemary J. Hughes,   Smollie Ncube,   Andrew Pelter,   Keith Smith,   Ei-ichi Negishi  and  Takao Yoshida  

Abstract

Reactions of trialkylboranes (R23B) with 1-lithio-1,1-bis(phenylthio)alkanes [R1(PhS)2C–Li+; R1= H or Prn], followed by reaction with mercury(II) chloride and oxidative work-up, give high yields of secondary (R1= H) or tertiary (R1= Prn) alcohols (R1R22COH).

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Article information

DOI
https://doi.org/10.1039/P19770001172
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1977, 1172-1176

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Synthesis of secondary or tertiary alcohols by reactions of trialkylboranes with acyl carbanion equivalents

R. J. Hughes, S. Ncube, A. Pelter, K. Smith, E. Negishi and T. Yoshida, J. Chem. Soc., Perkin Trans. 1, 1977, 1172 DOI: 10.1039/P19770001172

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