Irradiation of ethyl 4-subslituted 2-cyano-1,2-dihydroquinoline-1-carboxylates (Reissert compounds) in ethanol gives ethyl 6b-substituted 1-cyano-1,1a.2,6b-tetrahydrocycloprop[b]indole-2-carboxylates. The stereochemistry of the products has been determined by n.m.r. spectroscopy.
M. Ikeda, S. Matsugashita, F. Tabusa and Y. Tamura, J. Chem. Soc., Perkin Trans. 1, 1977, 1166 DOI: 10.1039/P19770001166
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