Photolysis of 5-endo-,7-anti-disubstituted bicyclo[2.2.1]heptan-2-ones gave cyclopentene aldehydes in good yield: the substituents were selected so that conversions into prostaglandin-C2(PG-C2) analogues were readily achieved.
N. M. Crossland, S. M. Roberts and R. F. Newton, J. Chem. Soc., Chem. Commun., 1977, 886 DOI: 10.1039/C39770000886
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