1-Adamantyl radicals react with several 2-substituted benzothiazoles to afford 2-(1-adamantyl)-benzothiazole as a result of a homolytic substitution occurring at the ipso position; the yields are greater when the groups to be displaced are electron-withdrawing.
M. Fiorentino, L. Testaferri, M. Tiecco and L. Troisi, J. Chem. Soc., Chem. Commun., 1977, 316 DOI: 10.1039/C39770000316
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