Binor-S, the {4 + 4} dimer of norbornadiene, rearranges in the gas phase on a platinum catalyst and in solution with silver perchlorate, yielding two new norbornadiene dimers which can be elaborated in three steps into triamantane via{4 + 2} adducts with butadiene; the structure of one dimer has been established by an X-ray crystal analysis.
R. Hamilton, M. A. McKervey, J. J. Rooney and J. F. Malone, J. Chem. Soc., Chem. Commun., 1976, 1027 DOI: 10.1039/C39760001027
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