Optically active O-methyl ethylphenylphosphinite (1) and S-ethyl ethylphenylthiophosphinite (2) have been shown to react with nucleophilic reagents like methyl-lithium and sodium methoxide with inversion of configuration at the chiral PIII centre.
J. Omelanczuk and M. Mikołajczyk, J. Chem. Soc., Chem. Commun., 1976, 1025 DOI: 10.1039/C39760001025
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