SCHEDULED MAINTENANCE
The nonequivalence of the diastereotopic isopropyl methyl groups in di-isopropylphenylsilyl-lithium up to 185 °C indicates that the barrier to inversion about silicon in the silyl anion is > 24 kcal mol–1.
J. B. Lambert, M. Urdaneta-Perez and H. Sun, J. Chem. Soc., Chem. Commun., 1976, 806 DOI: 10.1039/C39760000806
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