Issue 20, 1976
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis of [Os5(CO)15]2–, [HOs5(CO)15]–, and [H2Os5(CO)15]; X-ray crystal structure of [(Ph3P)2N]+[HOs5(CO)15]–

Colin R. Eady,   John J. Guy,   Brian F. G. Johnson,   Jack Lewis,   Maria Carlotta Malatesta  and  George M. Sheldrick  

Abstract

The complex [Os6(CO)13] reacts with methanolic potassium hydroxide to produce [Os5(CO)15]2– which, upon acidification, gives [HOs5(CO)15]– and [H2Os5(CO)15]; single crystal X-ray diffraction and 13C n.m.r. studies show the presence, within the anionic pentaosmium clusters, of trigonal bipyramidal metal arrangements.

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Article information

DOI
https://doi.org/10.1039/C39760000807
Article type
Paper

J. Chem. Soc., Chem. Commun., 1976, 807-809

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Synthesis of [Os5(CO)15]2–, [HOs5(CO)15]–, and [H2Os5(CO)15]; X-ray crystal structure of [(Ph3P)2N]+[HOs5(CO)15]–

C. R. Eady, J. J. Guy, B. F. G. Johnson, J. Lewis, M. C. Malatesta and G. M. Sheldrick, J. Chem. Soc., Chem. Commun., 1976, 807 DOI: 10.1039/C39760000807

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