The acid-catalysed rearrangement of β-hydroxyalkyl phenyl sulphides leads to phenylthio migration from a tertiary or secondary centre to a primary centre, and, when assisted by silicon, between two secondary centres or even from a secondary to a tertiary centre.
P. Brownbridge, I. Fleming, A. Pearce and S. Warren, J. Chem. Soc., Chem. Commun., 1976, 751 DOI: 10.1039/C39760000751
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