Issue 19, 1976

Unusual relaxation kinetics in the photo-induced planar ⇌ tetrahedral isomerization of dibromo[1,3-bis(diphenylphosphino)propane]nickel(II) in acetonitrile

Abstract

Three relaxation processes observed during the Q-switched laser photolysis of the title complex in acetonitrile are assigned to the relaxation of coupled equilibria involving planar and tetrahedral isomers of the complex together with ion-pairs and free ions.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1976, 749-751

Unusual relaxation kinetics in the photo-induced planar ⇌ tetrahedral isomerization of dibromo[1,3-bis(diphenylphosphino)propane]nickel(II) in acetonitrile

L. Campbell and J. J. McGarvey, J. Chem. Soc., Chem. Commun., 1976, 749 DOI: 10.1039/C39760000749

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