Unusual relaxation kinetics in the photo-induced planar ⇌ tetrahedral isomerization of dibromo[1,3-bis(diphenylphosphino)propane]nickel(II) in acetonitrile
Abstract
Three relaxation processes observed during the Q-switched laser photolysis of the title complex in acetonitrile are assigned to the relaxation of coupled equilibria involving planar and tetrahedral isomers of the complex together with ion-pairs and free ions.