The salts [SxI]+[MF6]–(x= 7 or possibly 8, M = As or Sb) have been prepared by various reactions; the crystal structure of [S7I]+[SbF6]– shows the cation to contain iodine bonded to a sulphur atom of a seven-membered sulphur ring.
J. Passmore, P. Taylor, T. K. Whidden and P. White, J. Chem. Soc., Chem. Commun., 1976, 689 DOI: 10.1039/C39760000689
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