Issue 12, 1976

Synthesis, and crystal and molecular structure of µ-dibromo-µ-tetraphenyl-diphosphane-bis[tricarbonylrhenium(I)], a molecule containing a new type of tetraphenyldiphosphane bridge

Abstract

No cleavage of the P–P bond occurs during the reaction of the tetrahydrofuran (thf) complex [Re2Br2(CO)6(thf)2] with P2Ph4 in toluene; an X-ray study shows that the resulting compound contains bridging tetraphenyldiphosphane in a unique type of bonding.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1976, 441-442

Synthesis, and crystal and molecular structure of µ-dibromo-µ-tetraphenyl-diphosphane-bis[tricarbonylrhenium(I)], a molecule containing a new type of tetraphenyldiphosphane bridge

J. L. Atwood, J. K. Newell, W. E. Hunter, I. Bernal, F. Calderazzo, I. P. Mavani and D. Vitali, J. Chem. Soc., Chem. Commun., 1976, 441 DOI: 10.1039/C39760000441

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