The reactions of 2-phenyl-1,3,2-dioxaphospholan (1) with acrylic acid (2a) and with acrylamide (2b) afford the pentacovalent cyclic acyloxy (3a) and amido-phosphoranes (3b), respectively.
T. Saegusa, S. Kobayashi and Y. Kimura, J. Chem. Soc., Chem. Commun., 1976, 443a DOI: 10.1039/C3976000443A
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