1-Adamantyl and other alkyl radicals, produced by the AgI-catalysed decarboxylation of carboxylic acids by (NH4)2S2O8, react with acyl-heteroaromatic bases effecting the displacement of the acyl group; a mechanism is proposed in which the reacting species is the radical cation of the heteroaromatic compounds.
M. Fiorentino, L. Testaferri, M. Tiecco and L. Troisi, J. Chem. Soc., Chem. Commun., 1976, 329 DOI: 10.1039/C39760000329
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