The synthesis of bicyclo[4.2.0]octa-2,4-dien-7-one has been accomplished by trapping this unstable tautomer with benzylideneacetoneiron tricarbonyl to form the stable bicyclo[4.2.0]octa-2,4-dien-7-oneiron tricarbonyl which was then oxidatively cleaved with ceric ammonium nitrate at –30 °C to yield the title ketone.
M. Brookhart, G. O. Nelson, G. Scholes and R. A. Watson, J. Chem. Soc., Chem. Commun., 1976, 195 DOI: 10.1039/C39760000195
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