It is proven that only the 2-pro-R hydrogen of MVA is retained at the 15α-position of sitosterol biosynthesized by excised petals of Calendula officinalis flowers.
J. K. Sliwowski and E. Caspi, J. Chem. Soc., Chem. Commun., 1976, 196 DOI: 10.1039/C39760000196
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