SCHEDULED MAINTENANCE
Lithium trans-alkenyltrialkylaluminates, prepared by the hydroalumination of alkynes followed by treatment with n-butyl-lithium, react with epoxides to produce β-hydroxy-substituted trans-alkenes, which are readily convertible into βγ-unsaturated carbonyl derivatives.
E. Negishi, S. Baba and A. O. King, J. Chem. Soc., Chem. Commun., 1976, 17 DOI: 10.1039/C39760000017
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