Issue 1, 1976

Chemical synthesis with metal atoms: preparation and X-ray structure of (η5-cycloheptadienyl)-(η5-cycloheptatrienyl) iron. A bifluxional molecule

Abstract

[Fe(η5-C7H7)(η5-C7H9)] has been prepared by cocondensation of iron vapour with cycloheptatriene; an X-ray analysis shows a sandwich structure with open faces of the two η5-systems skew to each other, and in solution two types of fluxional behaviour are exhibited.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1976, 16-17

Chemical synthesis with metal atoms: preparation and X-ray structure of (η5-cycloheptadienyl)-(η5-cycloheptatrienyl) iron. A bifluxional molecule

J. R. Blackborow, K. Hildenbrand, E. K. von Gustorf, A. Scrivanti, C. R. Eady, D. Ehntolt and C. Krüger, J. Chem. Soc., Chem. Commun., 1976, 16 DOI: 10.1039/C39760000016

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