Single crystals of fluorene, γ-irradiated at room temperature, have been studied using e.s.r. spectroscopy and the product of irradiation identified as the fluoren-9-yl radical. The components of the hyperfine coupling tensor have been determined, and the radical has been found to retain the same position as the parent molecule in the crystal lattice.
F. Barigelletti, G. Orlandi, G. Giro and G. Poggi, J. Chem. Soc., Faraday Trans. 2, 1975, 71, 1436 DOI: 10.1039/F29757101436
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