Rotational-vibrational infrared and Raman spectra have been calculated for the degenerate modes of a hypothetical free nitrate ion. Comparison of the computed spectra with results obtained for the nitrate ion in aqueous solution indicates that rotational motions are not the primary cause of the doublet structure of the ν3(E′) band.
D. J. Lockwood, J. Chem. Soc., Faraday Trans. 2, 1975, 71, 1440 DOI: 10.1039/F29757101440
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