Preparation, properties, and molecular structure of silylsulphinylamine
Abstract
We have prepared and characterised the unstable compound silylsulphinylamine, SiH3NSO, and report its vibrational, electronic, photoelectron, and n.m.r. spectra. Electron diffraction studies show that the skeleton is bent at nitrogen and at sulphur, has an unusually long Si–N bond, and is non-planar.