Issue 9, 1975
From the journal:

Journal of the Chemical Society, Dalton Transactions

The reaction between carbonatobis(phosphine)platinum(II) complexes and triorganotin hydrides. Formation of Sn–PtIV bonds

Colin Eaborn,   Alan Pidcock  and  Barry R. Steele  

Abstract

The triorganotin hydrides R3SnH (R = Ph, PhCH2, and o-, m-, or p-MeC6H4) react with [Pt(CO3)(PMe2Ph)2] in methanol to give the PtIV complexes cis,trans,cis-[PtH2(SnR3)2(PMe2Ph)2] and some similar complexes of PEt3, PMePh2, and diphos were obtained. In benzene the PtIV complexes lost hydrogen reversibly to form complexes such as trans-[Pt(SnR3)2(PMe2Ph)2], which may also be synthesised from the carbonate-complexes in benzene. The factors favourable to the isolation of the PtIV complexes are reported. The stereochemistries of the PtIV and PtII complexes were determined from 1H and 3 1P{1H}-n.m.r. spectra.

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Article information

DOI
https://doi.org/10.1039/DT9750000809
Article type
Paper

J. Chem. Soc., Dalton Trans., 1975, 809-813

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The reaction between carbonatobis(phosphine)platinum(II) complexes and triorganotin hydrides. Formation of Sn–PtIV bonds

C. Eaborn, A. Pidcock and B. R. Steele, J. Chem. Soc., Dalton Trans., 1975, 809 DOI: 10.1039/DT9750000809

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