Issue 7, 1975
From the journal:

Journal of the Chemical Society, Chemical Communications

Nickel complex-catalysed reaction of propylmagnesium bromide with butadiene. A highly stereoselective synthesis of cis- and trans-(2-vinylcyclopentyl)methylmagnesium bromide

Hugh Felkin,   Lawrence D. Kwart,   Gérard Swierczewski  and  J. David Umpleby  

Abstract

Propylmagnesium bromide, butadiene, and catalytic amounts of [(PPh3)2NiCl2] afford octa-2,7-dienyl-magnesium bromide; this cyclises to cis-(2-vinylcyclo-pentyl)methylmagnesium bromide, which can be thermally epimerised to the trans isomer.

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Article information

DOI
https://doi.org/10.1039/C39750000242
Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 242-243

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Nickel complex-catalysed reaction of propylmagnesium bromide with butadiene. A highly stereoselective synthesis of cis- and trans-(2-vinylcyclopentyl)methylmagnesium bromide

H. Felkin, L. D. Kwart, G. Swierczewski and J. D. Umpleby, J. Chem. Soc., Chem. Commun., 1975, 242 DOI: 10.1039/C39750000242

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