U.v. irradiation of pyridine-2-carbonitrile (1) in acidic ethanolic solution gives 6-ethoxypyridine-2-carbonitrile (2) and 2-(1-hydroxyethyl)pyridine (3); (2) is formed via an excimer and (3) by a radical mechanism.
T. Furihata and A. Sugimori, J. Chem. Soc., Chem. Commun., 1975, 241b DOI: 10.1039/C3975000241B
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