The exchange of but-l-ene on iron and nickel films proceeds by dissociative adsorption on the vinylic carbon atoms; the most reactive hydrogen atom in this reaction is that bound to C(2).
M. Ledoux, F. G. Gault, J. Masini and G. Roussy, J. Chem. Soc., Chem. Commun., 1975, 153 DOI: 10.1039/C39750000153
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