Restricted rotation on the n.m.r. time scale about the Rh–Ccarb bond in complexes [RhLEt(Y)Y′(Z)][LEt= [graphic omitted](Et)] is demonstrated; for trans-[Rh(LEt)2(CO)Cl], variable temperature observations provid rotational activation parameters including a relatively low activation energy (⩽ 10 kcal mol–1) and a negative activation entropy.
M. J. Doyle and M. F. Lappert, J. Chem. Soc., Chem. Commun., 1974, 679 DOI: 10.1039/C39740000679
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