Reaction of some nucleophiles with the nitro-sugar (1) under weakly acidic or neutral conditions results in the steroselective synthesis of products with the thermodynamically less stable manno-configuration.
T. Sakakibara and R. Sudoh, J. Chem. Soc., Chem. Commun., 1974, 69 DOI: 10.1039/C39740000069
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