The pulse radiolysis of pure or an NaBr solution of hexamethylphosphoric triamide (HMPT)(saturated either with Ar or N2O) suggests that the transient with a maximum absorption at 600 nm is due to a bromine atom charge-transfer complex giving an ionization potential for HMPT of 8·1 eV and also that the u.v. absorption is associated with an excited state of HMPT.
A. M. Koulkes-Pujo, L. Gilles, B. Lesigne, J. Sutton and J. Y. Gal, J. Chem. Soc., Chem. Commun., 1974, 71 DOI: 10.1039/C39740000071
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