4-Fluoropyridine has been synthesised by the Balz–Schiemann method and a procedure has been evolved for its isolation and purification. Its ready transformation into N-(4-pyridyl)-4-pyridone is an acid-catalysed process; under conditions in which this does not occur, the base is stable.
P. B. Desai, J. Chem. Soc., Perkin Trans. 1, 1973, 1865 DOI: 10.1039/P19730001865
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