The photoreaction of Co(en)33+ with Fe(CN)64– is shown to originate in an excited state of CoIII and hence to be the first example of efficient photoreaction of a cobalt–amine complex in a ligand field (L.F.) excited state.
N. A. P. Kane-Maguire and C. H. Langford, J. Chem. Soc., Chem. Commun., 1973, 351b DOI: 10.1039/C3973000351B
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