Changes with pH of the spectroscopic properties of aqueous solutions of bipyridyl complexes of platinum(II) are attributed to a reaction not at the metal ion but of the ligand, at its 6-position.
R. D. Gillard and J. R. Lyons, J. Chem. Soc., Chem. Commun., 1973, 585 DOI: 10.1039/C39730000585
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