Metal complexes of novel sulphur- and phosphorus-containing heterocycles. Preparation and structure of tricarbonyl-η4-(1-pentafluorophenyl-2,3,4,5,-tetrakistrifluoromethylthiophen)manganese and π-Cyclopentadienyl(1-hydroxy-2,3,4,5,-tetrakistrifluoromethylphosphole 1-oxide)cobalt

M. J. Barrow; J. L. Davidson; W. Harrison; D. W. A. Sharp; G. A. Sim; F. B. Wilson

doi:10.1039/C39730000583

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Metal complexes of novel sulphur- and phosphorus-containing heterocycles. Preparation and structure of tricarbonyl-η⁴-(1-pentafluorophenyl-2,3,4,5,-tetrakistrifluoromethylthiophen)manganese and π-Cyclopentadienyl(1-hydroxy-2,3,4,5,-tetrakistrifluoromethylphosphole 1-oxide)cobalt

M. J. Barrow, J. L. Davidson, W. Harrison, D. W. A. Sharp, G. A. Sim and F. B. Wilson

Abstract

Heterocyclic derivatives Mn(CO)₃(C₄F₆)₂SR and C₅H₅Co(C₄F₆)₂PF₃ are formed by reaction between hexafluorobut-2-yne and [Mn(CO)₄SR]₂, (R = CF₃, C₆F₅), and (π-C₅H₅)Co(PF₃)₂; these derivatives contain non-planar heterocyclic rings with non-bonding metal heteroatom separations.

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DOI: https://doi.org/10.1039/C39730000583
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1973, 583-584

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Metal complexes of novel sulphur- and phosphorus-containing heterocycles. Preparation and structure of tricarbonyl-η⁴-(1-pentafluorophenyl-2,3,4,5,-tetrakistrifluoromethylthiophen)manganese and π-Cyclopentadienyl(1-hydroxy-2,3,4,5,-tetrakistrifluoromethylphosphole 1-oxide)cobalt

M. J. Barrow, J. L. Davidson, W. Harrison, D. W. A. Sharp, G. A. Sim and F. B. Wilson, J. Chem. Soc., Chem. Commun., 1973, 583 DOI: 10.1039/C39730000583

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Journal of the Chemical Society, Chemical Communications

Metal complexes of novel sulphur- and phosphorus-containing heterocycles. Preparation and structure of tricarbonyl-η⁴-(1-pentafluorophenyl-2,3,4,5,-tetrakistrifluoromethylthiophen)manganese and π-Cyclopentadienyl(1-hydroxy-2,3,4,5,-tetrakistrifluoromethylphosphole 1-oxide)cobalt

Abstract

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Metal complexes of novel sulphur- and phosphorus-containing heterocycles. Preparation and structure of tricarbonyl-η⁴-(1-pentafluorophenyl-2,3,4,5,-tetrakistrifluoromethylthiophen)manganese and π-Cyclopentadienyl(1-hydroxy-2,3,4,5,-tetrakistrifluoromethylphosphole 1-oxide)cobalt

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