Several monocarbon monoxide complexes of iron(II) with a macrocyclic ligand have been prepared, and a crystal structure of one of these complexes shows that the Fe–C![[triple bond, length half m-dash]](https://www.rsc.org/images/entities/char_e007.gif)
O angle is linear, 178°, with an Fe–C distance of 1·75 Å and an unusually long axial Fe–N distance of 2·12 Å.
V. L. Goedken, J. Molin-Case and Y. Whang, J. Chem. Soc., Chem. Commun., 1973, 337 DOI: 10.1039/C39730000337
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