A simple and general explanation for the title phenomena is proposed in terms of ion-dipole or ion-ion interactions between the leaving group and participating base.
J. Závada, M. Pánková, M. Svoboda and M. Schlosser, J. Chem. Soc., Chem. Commun., 1973, 168 DOI: 10.1039/C39730000168
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