Base-induced dehydrobromination of tetra-substituted β-bromohydroperoxides to allylic hydroperoxides proceeds without cleavage of the carbon-oxygen bond; this observation excludes intermdiate perepoxides and suggests the operation of an intramolecular E2 reaction.
J. E. Baldwin and O. W. Lever, J. Chem. Soc., Chem. Commun., 1973, 343 DOI: 10.1039/C39730000343
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