The photoconversion of substituted arylazirines (1) into methoxyimines (3) proceeds via a nitrile ylide intermediate (2); deuterium labelling results indicate that the electron density is highest on the disubstituted carbon atom of the nitrile ylide.
A. Padwa and J. Smolanoff, J. Chem. Soc., Chem. Commun., 1973, 342b DOI: 10.1039/C3973000342B
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