In the symmetrical trans-complex (N-Bz-L-Pro)Cu(N-Bz-D-Pro) both benzyl groups are directed towards the apical positions, whereas in trans-Cu(N-Bz-L-Pro)2 one benzyl radical is twisted in the opposite direction, distorting the chelate ring from planarity.
G. G. Aleksandrov, Yu. T. Struchkov, A. A. Kurganov, S. V. Rogozhin and V. A. Davankov, J. Chem. Soc., Chem. Commun., 1972, 1328 DOI: 10.1039/C39720001328
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