The crystal structures of tris(ethylenethiourea)-copper(I) sulphate and tris(tetramethylthiourea)copper(I) tetrafluoroborate have been determined and both shown to contain Cu(I) and three sulphur atoms in a planar arrangement.
M. S. Weininger, G. W. Hunt and E. L. Amma, J. Chem. Soc., Chem. Commun., 1972, 1140 DOI: 10.1039/C39720001140
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