Ethyl NN-dimethylcarbamate, isopropyl NN-dimethylcarbamate, and t-butyl NN-dimethylcarbamate undergo β-elimination during gas-phase thermolysis; the influence of structure on rates and activation energies shows that the reactions which are unimolecular involve heterolytic rather than homolytic bond fission and support an unsymmetrical transition state.
N. J. Daly and F. Ziolkowski, J. Chem. Soc., Chem. Commun., 1972, 911 DOI: 10.1039/C39720000911
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...