Two types of palladium(II) complex, Pd(C4H4O3)(PPh3)2 and Pd(C2H2O2)(PPh3)(py), containing a carbon-bonded chelate ring of acetic anhydride and acetic acid, respectively, have been prepared by reactions of Pd(O2)(PPh3)2 with keten, and their molecular structures have been determined by X-ray diffraction.
S. Baba, T. Ogura, S. Kawaguchi, H. Tokunan, Y. Kai and N. Kasai, J. Chem. Soc., Chem. Commun., 1972, 910 DOI: 10.1039/C39720000910
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