Acetolysis of the tetracyclic epimeric alcohols, precursors of the biogenetic intermediate postulated by Edwards, which were prepared from Δ8(14)-podocarpen-13-one via a photochemical adduct with dichloroethylene, leads to (+)-14α-hibyl acetate, ultimately converted into (+)-14α-hibaone.
D. K. M. Duc, M. Fetizon and J. Flament, J. Chem. Soc., Chem. Commun., 1972, 886 DOI: 10.1039/C39720000886
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