RhI catalysed rearrangements of vinyl epoxides to αβ-unsaturated aldehydes and cleavage of oxetans to olefins and aldehydes are described and the reactions interpreted in terms of RhI acting as a weak Lewis acid.
G. Adames, C. Bibby and R. Grigg, J. Chem. Soc., Chem. Commun., 1972, 491 DOI: 10.1039/C39720000491
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