The stereochemistry of the predominant mode of addition of singlet oxygen to vinylene diethers to yield 1,2-dioxetans is unequivocally established as cis with respect to the olefin.
A. P. Schaap and N. Tontapanish, J. Chem. Soc., Chem. Commun., 1972, 490 DOI: 10.1039/C39720000490
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